![]() Lily Allen looks emotional as she greets fans after second night starring in in her new West End play The Pillowman A hailstorm of one-liners has turned into a lukewarm drizzle, writes LIZ JONESĪlessandra Ambrosio gives hint of her midriff by wearing unbuttoned pants with tank top on lunch date with look-alike daughter Anja in Beverly Hills Harrison Ford, 80, cosies up to his stunning wife Calista Flockhart, 58, at the star-studded Indiana Jones premiere in GermanyĪnd Just Like That. Vanessa Kirby exudes glamour in a black velvet gown as she hits the red carpet at Mission: Impossible 7 Lizzie Cundy shows off her very ample cleavage in a skimpy print bikini as she celebrates role as Miss England pageant judge with a racy post Unlock the secret to quality sleep: Shoppers say these 'desert island must-have' liquid drops allow them to fall asleep 'within SECONDS' ![]() Kevin Costner's estranged wife Christine gushes over meeting 'charming movie star' when she was 18 Madonna's twin daughters Stella and Estere, 10, graduate from elementary school as superstar celebrates milestone by sharing photo of duo as Cindy Beale's 26-year backstory is FINALLY revealed Jacqueline Jossa shocks EastEnders fans as she makes a surprise return to the soap. Hailey Bieber makes her sun-kissed skin pop in a bright white maxi dress during girls' day with BFF Justine Skye in West Hollywood Katie Holmes teases her toned figure through a crochet dress as she leads stars at opening night of the American Ballet Theatre's summer season 'Headlining Carousel 2!' Noel Gallagher plays impromptu gig at airport baggage reclaim area - but his very small audience look unimpressed Jennifer Lawrence steps out in casual chic style in plain white T-shirt with Tiffany & Co. 'It was devastating': Louis Tomlinson sends heartfelt message to his fans after hailstone storm at his Colorado concert left 90 injured 'The blueprint of all bombshells is back!!' Love Island fans are sent into a frenzy as it's revealed Kady McDermott will make a shock return to the villaĬhristina Aguilera gives her edgy all-black outfit a pop of color with a pastel pink handbag as she steps out in NYC ahead of her Pride concertĪrnold Schwarzenegger and girlfriend Heather Milligan bike to Gold's Gym where he poses for selfies with fans before son Joseph Baena arrives for his workoutĬardi B congratulates 4-year-old daughter Kulture from graduating pre-school: 'My baby moving on up'Īshley Graham flaunts her figure in a turquoise two-piece as she plugs her St Tropez self-tanning kit while poolside Lauren Goodger's ex Charles Drury is charged with assaulting the TOWIE star on the day of their baby daughter's funeral Proud parents Priyanka Chopra and Nick Jonas dote on daughter Malti in sweet new snaps Jennifer Lawrence the Vanderpump Rules super-fan throws SHADE at reality TV villain Tom Sandoval after his affair with Raquel Leviss Victoria Pendleton's twin brother Alex, 42, dies after 'epic battle' with brain tumour: Olympian pays tribute to her 'kind, brave twinnie' 'I feel b****y beautiful!' Stacey Solomon is praised by fans for showing off her figure in unedited swimwear snaps four months after giving birth just days after welcoming his fourth child Roman with 29-year-old girlfriend Noor AlfallahĬristiano Ronaldo's girlfriend Georgina Rodríguez shows off her gorgeous curves in a green bikini as they enjoy family time on superyacht in Sardinia just weeks ahead of 35th wedding anniversaryĪl Pacino, 83, spotted out for a stroll in Los Angeles. ![]() Fox honors his devoted wife Tracy Pollan on her birthday. PICTURED: Shannen Doherty flashes brave smile as she emerges for first time since revealing breast cancer spread to her brain Taylor Swift cuts casual figure in Philadelphia Eagles sweatshirt and tiny black shorts as she arrives at NYC music studio ![]()
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![]() ![]() Gadka’s Magical Oddities (Tarheel Promenade)įar from the most reputable shopkeeper in town, the dwarf Gadka Burtannon still manages to do a brisk trade in interesting magic items. ![]()
![]() ![]() ![]() Insurgents clash with Special Forces over the downed Hind This could of course be just not enough time to look around properly or the fact that October is now brimming over with conventions, SELWG on the 17th and FIASCO on the 31st plus Battleground and Warfare in November so maybe traders are taking it steady in the post pandemic times. On the trade front it did seem a bit thin the stalwarts were there, Foundry, Warlord, Empress, Dave Thomas, and Warlord and Foundry occupied a significant amount of hall space but I did have a feeling of something missing. Syrian NDF deploy outside the police stationĮlsewhere in the hall were some excellent games, none of which we managed to take a picture of, but from memory the outstanding ones for us were a 28mm Plains Indians War game, excellent Indian village and what looked to be quite an innovative basing system – wish I could have stopped and chatted about this, a superb looking C18th game complete with star fort and two enormous galleons out to sea (I mean the size of the things you see in antique shops!), very visually arresting, an excellent looking El Cid game, although I couldn’t see Charlton Heston □ and a quite extraordinary 60/70mm ancients Macedonian v Persian game – wow! Insurgents take the high ground The rules were Spectre Operations V2 which we are fairly confident with these days hence the numerous factions (9 different units in the end plus armour support) but as we were at a show and we knew we’d get distracted we didn’t deploy all in one go but rather fed them on as we went. We took along our Syrian Civil War city streets game with the superb terrain from Task Force Terrain and had our streets populated by the crew of a downed Hind, Syrian Special Forces on a search & rescue mission, various representations of the numerous insurgent factions and Hezbollah units bolstering the government forces. Conventions are back! Much awaited and much anticipated we were back at The Other Partizan on Sunday October 10th and it was like we hadn’t been away □ Everyone was super excited and there were some excellent games on display although our chance to to view them was restricted by it being just the two of us this year and so our time was taken up with our own game. ![]() ![]() ![]() Is the folder full of dat plist xml files supposed to be an invisible folder that MacOS uses for tracking states of the primary Documents folder? If so, should I be concerned that it is visible and subject to accidental file operations like saving documents into it, deleting it, etc. ![]() My main concern is that the Documents folder has special status in MacOS (which I don't fully grok) and I want to be sure nothing in the file structure is corrupted in a way that will affect backups, integrity, etc.So, I have concerns and questions, I hope someone can help me out: dat files from the second folder, they appear to be dated state snapshots of some kind: (Log in to your Apple ID if you aren’t already logged in). dat files are xml files, apparently plists, named by date with this header:Īnd then a ton of these items: data alt 65.225685119628906 currentSpeed 3.0155007839202881 date horizontalAccuracy 4.6371793746948242 lat 48.537681579589844 long -122.22262573242188 runs 8 verticalAccuracy 3.5101432800292969 Open System Preferences (click on the Apple logo in the top left and then System Preferences). Use your Apple ID or create a new account to start using Apple services. Sign in with your Apple ID and password if prompted. Sign in to iCloud to access your photos, videos, documents, notes, contacts, and more. Then click on System Preferences > iCloud. The second Documents icon has a folder icon with some kind of illustrative navigation app-looking icon on it and only contains. Apples iCloud service is not recommended for preferences syncing, due to iClouds default use of Optimised Storage, as well as being significantly slower and. So, to back up your Mac to iCloud, you have to sync your macOS to the storage space of the iCloud drive provided by Apple, and here’s how you can do that: First, click on the Apple logo at the top of your Mac computer.So far, mostly normal stuff except for the blank folder icon when viewed through. This is the folder I'm used to seeing as a MacOS-recognized default document folder, though I don't know why the version uses a blank folder icon.Now, select the different files or data that you want to add to the iCloud backup, for example, photos, videos, emails, etc. Sign in with your Apple ID and password if prompted. One has a traditional Documents Folder folder icon (simple debossed document icon on the folder icon) when viewed in the Finder. First, click on the Apple logo at the top of your Mac computer.In the pictures folder of my Mac I have a 'Scansioni' subfolder, I would like to synchronize this folder with iCloud in order to have a backup copy but I dont know how to synchronize folders other than those established by default by iCloud. Sign in via System Preferences on a Mac and then select the Sign in. How to synchronize any folder in iCloud Hello. Looking at my iCloud Drive (through online or through the Finder on my Mac) I see two Documents folders. 1.iCloud Drive will only work when youre signed in to your devices with your Apple ID. ![]() ![]() ![]() ![]() Pumpkin Spice Latte Nutritional Information 390 calories 50 grams sugar. You want to pull out your fall decor and start munching on PSLs in a big sweater but the September heat hasn't quite cleared the forecast. Pumpkin Cream Cold Brew is ideal for that mid-season. Nutritional Information 250 calories 31 grams sugar. Ooo adult hot chocolate! I want to fill my bathtub with it, cover myself in marshmallows and spend the day… Pumpkin Cream Cold Brew. Nutritional Information 370 calories 35 grams of sugar. › Drink › The Nation Best Starbucks Drinks All 40 Drinks on the Menu Ranked… › Drink › The Nation Cashed Cafe Mocha. Instagram/Starbucks.Īll 40 drinks ranked on the Best Starbucks Drinks Menu… starbucks Advertisement – Continue Reading Below Iced Matcha Latte A hot matcha latte is great but it offers the same familiar caffeinated flavor in a refreshing cold drink option. cold brew A classic – worthy of its high place on this list. The PSL is a perfect sampler as is but making a cold brew version is great for those who opt for an iced drink all year round. About three Dailyh editors' eyes lit up when I mentioned the drink I grew up on that stuff. There's something nostalgic about a caramel macchiato. › g24445159 › best-starbucks-drinks24 Best Starbucks-drinks Ever – Most Famous… – Delish › g24445159 › best-starbucks-drinks CachedVideo Duration 3 minIced Caramel Macchiato. 1.13 The 21 Best Starbucks Drinks of 2023 Ranked and Reviewed (with…įind deals on beverage products on Amazon.Ģ4 Best Starbucks Drinks Ever – Most Popular … – Delish.1.12 Featured Menu Starbucks Coffee Company.1.11 15 TikTok Starbucks Drinks to Try in 2023 – Delish.1.10 25 Best Starbucks Drinks for First-Timers (2023).1.9 Best Starbucks Drinks to Try Today! (Updated) – Coffee Geek.1.8 27 Best Coffee Drinks at Starbucks 2023 Must Try.1.7 Starbucks Secret Menu 52 Best Drinks and How to Order Them 2023.1.6 27 Best Starbucks Drinks – Taste of Home.1.5 60 Starbucks Secret Menus You'll Love in 2023.1.4 Starbucks Secret Menu 60 Best Drinks to Order in 2022.1.3 All 40 drinks ranked on the Best Starbucks Drinks Menu….1.2 24 Best Starbucks Drinks Ever – Most Popular … – Delish.29339700+ followers on FacebookShop Beverages – official site. ![]() ![]() ![]() On the next page, we'll see tiles that DO flip over. ![]() The cats and the ducks are also "tiles" that translate/slide/glide left or right, up or down, to fill in the picture. Learn how its done with our example and try it out with our practice problems. Now take a look at the other pictures on this page. Translations and reflections are two ways of how tessellations are created. The original line XY is "translated" along the Y axis to make line X 1Y 1. Examples of Tessellations: Not Examples of Tessellations: Now that we know what a tessellation is, how do we make one We have four different ways to create your own tessellations Getting Started: Beginner Tessellation No cutting is involved for this starter tessellation design, making it a great starting project for younger artists. In math class, we'd say that we can move a line along a graph by saying "X=Y" for the original line and "X 1 + 4 = Y 1" for the line that would be 4 boxes above it on a piece of graph paper. So, why do we call it "translation"? Well, we call that movement a "translation" because we "translate" the tile along the X-axis and the Y-axis. This kind of tessellation symmetry- tile repeating- is called Translation and/or Sliding. The tiles in this picture are copies of one another that are simply shifted from one place to another, without tilting or flipping them over or resizing them. ![]() It was constructed by the Muslim Moors in the 14th century and became the royal residence and court of Mohammed ibn Yusuf Ben Nasr. It also explains how they can be transformed using translation, rotation. The tessellation is made by repeating the tile over and over again, and fitting all the copies of the tile together. One of the most famous examples of Islamic tessellation art is in the Alhambra, a huge palace located in Granada, Spain. It shows a simple visual demonstration of tessellating triangles, squares and hexagons. This is the basic "tile" shape of the first tessellation on this page. How to Make an Asian Chop (stone stamp). ![]() ![]() ![]() Some people don’t even want to try hunting for codes in a sea of scammers. Share Your Bandwidth Through Pawnsĭesigning your own game might not be an option for everyone. While this might not be the optimal way to get some Robux, it can come in handy if you need to get rid of some items and make some Robux quickly. However, keep in mind that Roblox takes 30% off every transaction. Set your price in Robux and wait for them to accept. Just head to a player’s profile and offer them a trade. If you have items that other players might want and you don’t need them anymore, you can trade them for Robux. Here’s another option that requires a Roblox Premium membership. Note: This offer is only available to US residents. Enter the code you got from Microsoft and enjoy your free Roblox Robux!.Run Roblox, select Gift Cards, and then Redeem Card.You’ll get an email from Microsoft with a Robux gift card.Choose the amount of points you want to exchange and click Confirm.Go to the Redeem page and select Roblox Digital Code from the list.Once you sign up for Microsoft Rewards and gather enough points: If you earn 1,500 Microsoft Reward points, you can exchange them for 100 Robux. Microsoft has a free program that allows users to earn rewards for using Microsoft Edge and other software. Set your price in Robux under Item for Sale, and you’re ready to go!.Select the gear icon in the bottom right and choose Configure from the menu.Open the template in any image editor and create your design.Once you select the category, you’ll get a link to a template.Go to the Create section and choose Shirts, Pants, or T-shirts from the menu. ![]() ![]() Premium users can create and sell unique clothing items like pants and shirts. While this option is only available to people with Roblox Premium membership, it might be worth a shot. Once your game generates some buzz, you can offer a special pass or in-game items players can purchase with roblox. Whatever you decide to create, make sure your game is fun and exciting, so it attracts as many players as possible. If your creation becomes popular, it can turn into an endless source of free Robux. Make Your Own Roblox GameĬreating your own game in Roblox isn’t the easiest way to get Robux, but it’s the most effective one. Also, some of these sites even ask for your account information and other sensitive data. Soon enough, you’ll realize tasks just keep coming with no Robux in sight. Most of them have a “human verification” process that has you complete a task. Many websites offer “Robux generators,” claiming they can get you thousands of free Robux. Keep in mind that there are a lot of scammers out there. Just keep in mind that they expire pretty quickly. You can find promo codes online fairly easily. This will automatically add Robux or special in-game items to your account. When you come across a promo code, all you need to do is redeem it on the Roblox website. Promotional Roblox codes will get you some free Robux if you’re in the right place at the right time. You can play premium games, participate in special in-game activities, change your username, and much more.įor those who don’t want to reach for their wallet, here are X ways to get free Roblox Robux! Use Robux Promo Codes While it’s not mandatory, Robux can significantly improve your experience with the platform. The easiest way to get it is by purchasing it (with real money). Robux is the currency used in Roblox to purchase games or in-game items. People all over the world have embraced the versatility provided by the platform, and it currently offers over 20 million games! Six Ways to Get Free Roblox Robux Right Now ![]() You could think of it more like a video game platform than a game since users create all the content instead of developers. Roblox is a creative online platform and storefront that allows users to make games, share them, and enjoy other people’s creations. ![]() ![]() ![]() Please see our Amazon Global Store Returns policy and Refunds policy for more information about returning Amazon Global Store items.Ĭamera, Electronics and PC Returns Policy ![]() Please see About Marketplace Returns & Refunds for details on Seller returns policies. To return faulty items see our Returning Faulty Items policy.įor items ordered on from a seller that fulfils and ships its own inventory (also called a third party seller), any returns will be in accordance with the returns policy set by that seller (not the Amazon AU returns policies). This change of mind return policy is in addition to, and does not affect your rights under the Australian Consumer Law including any rights you may have in respect of faulty items. Unless otherwise stated, original shipping fees for change of mind returns are not refunded. ![]() Please Contact Us and see About Items That Can’t Be Returned. In some circumstances, these items may be eligible for a refund or a replacement (for example, if you receive the wrong item due to an Amazon AU error or if the item is faulty). In some cases, the nature of the item means that it is non-returnable, for example, due to hygiene/health and personal care/wellness/consumable nature of the product. You can return most new, unopened items fulfilled by Amazon AU within 30 days of receipt of delivery for a replacement or full refund of the price you paid for the item if you change your mind - see About Replacements and About Refunds. ![]() ![]() ![]() It’s powerful, without the limitations of being corded, the battery has enough power to keep you trimming for over an hour and it’s quick to recharge too. It’s hard to find a negative about the RYOBI RY40204A and we think it’s the best cordless electric weed eater on the market. Got a lot of yard work to do? Be sure to check out our guide to the best gas lawnmowers and the best electric mowers too. Electric models are now more powerful and efficient than ever, so they will be more than enough to clear your yard and keep it looking tidy. Gas-powered weed eaters cost more to run and maintain and are louder and heavier than electric weed eaters. A gas-powered weed eater would be overkill, as a battery-powered or standard electric weed eater is sufficient to remove the weeds from your garden. Besides looking awful, weeds also suck a lot of the water and nutrients out of the earth, which can damage surrounding plants or grass.Īs you may have noticed, there has been no mention of gas-powered weed eaters. Weed eaters are an easy way to keep weeds at bay so that your yard can look as good as possible. Electric weed eaters make the process much easier and are available cordless or battery-powered - both are effective and will help solve your weed problems. ![]() You can manually pull weeds, but this is a tedious, laborious process, and for many people, the back pain is not worth it. Weed eaters are a safe way to remove weeds without using harsh chemicals that could harm your pets, children, or the environment. The best electric weed eaters are great for helping with your lawn and yard maintenance by helping you keep stubborn weeds off of the edges of your patio or tiles. ![]() ![]() ![]() One electron each comes from H, H, Cl, and Cl atoms: 1s1 of each H and 3pz1 of each Cl. Each of these hybrid orbitals has one electron and can accept one more. These four orbitals hybridize together to form four identical sp3 orbitals, all of which have the same energy. 2s, 2px, 2py, and 2pz orbitals of carbon are now half-filled. Let us look at the ground state electronic configuration of each atom in CH2Cl2 in terms of the orbitals.Ĭarbon, in the excited state, has one of the 2s electrons promoted to 2p therefore, the electronic configuration becomes 1s22s22px12py12pz1. The formula for the formal charge is as follows.įormal charge (FC) = Valence electrons – 0.5*bonding electrons – non-bonding electronsįor carbon, FC = 0 for hydrogen, FC = 0 and for Cl, FC = 0.Ī bond is formed between two atoms by the virtue of the overlap of orbitals on two atoms as these orbitals share electrons. Let us calculate the formal charges on each of the constituent atoms. The molecule is neutral, i.e., there is no charge on it. Simultaneously, both hydrogen atoms will achieve their respective duplets, and both chlorine atoms will achieve their respective octets, and thereby the situation will be a win-win for all five atoms.Ĭarbon will be singly bonded to H, H, Cl, and Cl, as shown in the Lewis structure. Two hydrogen atoms and two chlorine atoms can help carbon achieve this feat! Carbon needs 4 more electrons for its octet to be complete. Now, we shall construct a skeleton of the molecule with carbon as the central atom. In CH2Cl2, carbon satisfies this condition (4 electrons short of the octet versus 1 for chlorine). The central atom is the one that has the highest bonding capacity it is the atom that is the shortest of the octet. Next, we shall figure out the central atom to which the rest of the atoms shall be bonded. The number of valence electrons is therefore 7, and hence Cl needs 1 more to achieve the octet. K shell has 2 electrons, L shell has 8, and M shell has 7 electrons. Similarly, the atomic number of hydrogen is 1 thus, each H has 1 electron and needs 1 more to achieve the duplet. To achieve the octet, carbon needs 4 more electrons. Thus, the number of valence electrons is 4. There are 2 electrons in its K shell and 4 electrons in the L shell. The atomic number of carbon is 6 therefore, it possesses 6 electrons in its neutral form. We shall start by calculating the number of valence electrons in each atom of CH2Cl2 in order to see how short an atom is from an octet (or duplet in the case of hydrogen). ![]() Let us take a look at the chemical bonding represented by Lewis structure in CH2Cl2. Hydrogen, however, does tend towards a duplet, not octet, because it has only one electron in its K shell, and thus needs only one more to achieve the maximum capacity of the K shell. Please note that several atoms follow the octet rule, i.e., they tend to achieve eight electrons in their valence shell through chemical bonding this is reflected in the Lewis structure of the molecule. The structures drawn using this theory are termed Lewis (dot) structures. The purpose of this theory is to help visualize the chemical bonding of atoms in molecules.Įlectrons are represented as dots, and each pair of bonding electrons between two atoms is shown as a line. (We will discuss electronegativity in more detail in Unit 2 the electronegativity trend for second row elements are: Li < Be < B < C < N < O < F, with F being most electronegative.The Lewis theory of chemical bonding-although quite primitive and the most limited theory on electronic structure-does help one to determine how valence electrons are arranged around the constituent atoms in a molecule. Lewis structures with negative formal charges on more electronegative atoms are preferable.A Lewis structure with formal charges of the same sign (both + or both −) on adjacent atoms is less likely.The smaller the magnitude of the formal charges, the better.The fewer atoms with nonzero formal charges, the better.For an uncharged molecule, a Lewis structure in which all atoms have a formal charge of zero is preferable.Therefore, if following the steps for drawing Lewis structures leads to more than one possible arrangement of electrons and/or atoms for a given molecule, formal charges can help to decide which arrangement is likely to be the most stable, and hence the most likely Lewis structure for the given molecule. ![]() While formal charges do not portray the true electron density distribution within a molecule, they nonetheless account for electron arrangement in a Lewis structure in units of whole electron. Using Formal Charge to Predict the Most Likely Lewis Structure ![]() |
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